Synthesis and post-polymerisation modifications of aliphatic poly(carbonate)s prepared by ring-opening polymerisation
نویسندگان
چکیده
منابع مشابه
Monotelechelic poly(p-phenylenevinylene)s by ring opening metathesis polymerisation.
Poly(p-phenylenevinylene)s (PPVs) with single reactive end groups have been prepared with high molecular weights, narrow polydispersities (ĐM) and excellent end functionality (f). PPVs functionalised with α-bromoester end groups are effective macroinitiators in the atom transfer radical polymerisation (ATRP) of methyl methacrylate (MMA).
متن کاملMEH-PPV by microwave assisted ring-opening metathesis polymerisation.
Excellent control in the synthesis of MEH-PPV can be achieved by microwave assisted, ring-opening metathesis polymerisation (ROMP) of [2.2]paracyclophanedienes.
متن کاملPrecise synthesis of poly(macromonomer)s containing sugars by repetitive ring-opening metathesis polymerisation.
Various poly(macromonomer)s containing sugars have been prepared by ROMP of norbornene macromonomers substituted with ROMP block copolymers containing acetal-protected sugars as the side chain, which upon removal of the protecting group affords a novel amphiphilic architecture.
متن کاملNew developments on the ring opening polymerisation of polylactide
Polylactides (PLA), biodegradable aliphatic polyesters, produced solely from renewable resources may substitute petrochemically based polymers in a broad range of applications in the near future, if we manage to produce them at lower cost and higher efficiency as nowadays. Possible applications include food packaging for meat and soft drinks, films for agro-industry and non-wovens in hygienic p...
متن کاملSynthesis and rac-lactide ring-opening polymerisation studies of new alkaline earth tetrahydroborate complexes.
Reaction of K[HC(C(Me)NAr')(2)] (Ar' = 2,6-C(6)H(3)(i)Pr(2)) with Mg(BH(4))(2) afforded the pseudo four-coordinate tetrahydroborate complex Mg{HC(C(Me)NAr')(2)}(BH(4))(THF) (1). The corresponding reaction of Ca(BH(4))(2)(THF)(2) or Sr(BH(4))(2)(THF)(2) gave the pseudo five-coordinate analogues M{HC(C(Me)NAr')(2)}(BH(4))(THF)(2) (M = Ca (2) or Sr (3)). All three compounds 1-3 have been structura...
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ژورنال
عنوان ژورنال: Chem. Soc. Rev.
سال: 2013
ISSN: 0306-0012,1460-4744
DOI: 10.1039/c2cs35268k